catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO 1)(3-hydroxyadamantane-1-carboxylic acid-κO 1)zinc(II)]-μ2-4,4′-bipyridine] monohydrate]
نویسندگان
چکیده
In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Formula: see text]01]. O-H⋯O hydrogen bonds help to consolidate the packing.
منابع مشابه
Poly[[μ-aqua-bis(μ-4,4′-bipyridine-κ2 N:N′)bis(μ-3-hydroxyadamantane-1-carboxylato-κ2 O:O′)bis(3-hydroxyadamantane-1-carboxylato-κO)dicobalt(II)] heptahydrate]
The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy-droxy-adamantane-1-carboxyl-ate anions (L), one water mol-ecule, two bridging 4,4'-bipyridine (4,4'-bpy) ligands and seven uncoordinated water mol-ecules. Both of the Co(II) ions are coordinated in a distorted octa-hedral geometry. Four L ligands bind to e...
متن کاملcatena-Poly[[bis(2,4-dichlorobenzoato)bis(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′]
In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4'-bipyridine ligands. The bipyridine ligands also lies on a two...
متن کاملcatena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ3 O 1,O 1′:O 1;κ3 O 1:O 1,O 1′-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ2 N:N′] dinitrate]
In the title coordination polymer, {[Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)](NO(3))(2)}(n), the 3-(4-carb-oxy-phen-oxy)propionate monoanion O,O'-chelates to a Cd(II) cation through the aliphatic carboxyl-ate end. One of these O atoms is also connected to the metal cation from an inversion-related metal atom. The five O atoms bonded to the metal centre form a penta-go...
متن کاملcatena-Poly[[[(2-phenylacetato-κO)zinc(II)]bis[μ-4,4′-(disulfanediyl)dipyridine-κ2 N:N′]] monohydrate]
In the title compound, {[Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2)S(2))(2)]·H(2)O}(n), the Zn(II) atom is coordinated by four N atoms from four 4,4'-(disulfanedi-yl)dipyridine (bpds) ligands and two O atoms from two 2-phenyl-acetate anions in a distorted octa-hedral coordination geometry. The two bpds ligands of the same axial chirality bridge Zn(II) atoms, generating repeated rhomboidal chains, which ...
متن کاملcatena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ2-oxalato-κ4 O 1,O 2:O 1′,O 2′]
In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octa-hedral coordination geometry defined by the O atoms of two dimethyl-formamide mol-ecules and four O atoms of two bidentate oxalate ligands. The oxalate anion is located on an inversion centre and bridges two metal ions, resulting in a p...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011